Processes for the conversion of myrcene to nerol and citral

Details Processes for the conversion of myrcene to nerol and citral Processes for the conversion of myrcene to nerol and citral

1988-11-09

1991-05-21

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

C07C 4702

Patent

active

050177265

ABSTRACT:
A novel process for converting myrcene to a key palladium-myrcene complex using palladium (II) chloride in the presence of an aqueous cycloamide solvent and lithium salt is disclosed. Novel processes for converting the palladium-myrcene complex to citral using a phosphine compound, or to nerol using a nitrogen-donor compound in the presence of hydrogen gas, are also presented.

REFERENCES:
patent: 3382276 (1968-05-01), Schenck
patent: 3493619 (1970-02-01), Marbet
patent: 4226744 (1980-10-01), Naf

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