Thermosetting epoxy resin compositions and thermosets therefrom

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...

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428209, 428901, 523445, 523458, 523466, 523468, 525113, 525389, 525396, 525415, 525423, 525438, 525468, 525504, 525523, 525525, 525526, 525906, 525 90, 525 93, 525109, 525119, 525129, 525315, C08L 6300, C08G 5950, C08K 304

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active

048228320

ABSTRACT:
Described are novel thermosetting epoxy resin compositions suitable for making cured resins, prepregs and stiff, tough thermoset composites. The thermosetting compositions comprise a polyepoxide component, an amine hardner and a specified amount of certain aromatic oligomers containing functional groups which are reactive with the polyepoxide and/or hardener under curing conditions for the composition. The cured resins have a multiphase morphology which comprises at least one glassy continuous phase and at least one glassy discontinuous phase and have a fracture toughness, K.sub.IC, of at least 1.0 MPam.sup.1/2.

REFERENCES:
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patent: 4430473 (1984-02-01), Brode et al.
patent: 4645803 (1987-02-01), Kohli et al.
Addition of Polyethersulphone to Epoxy Resins-The British Polymer Journal, 15, 71-75 (1983).
Phase Separation in Epoxy Resins Containing Polyethersulphone-Bucknall and Partridge, Polymer, 24, 639-646 (1983).
Deformation and Fracture Behaviour of a Rubber-Toughened Epoxy: 1. Microstructure and Fracture Studies, Polymer, 24, 1341-1354 (1983), Kinloch, Shaw, Tod, and Hunston.
High Temperature Polymers, I-Sulfone Ether Diamines as Intermediates for Tractable High Temperature Polymers, Journal of Polymer Science 12, 565-573 (1974), Kawakami, Kwiatkowski, Brode and Bedwin.
Development of Resins for Damage Tolerant Composites-A Systematic Approach, 29th National Sampe Symposium, Apr. 3-5, 1984, 422-436, Diamont and Moulton.

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