Poly(oxyalkylene) modified phthalocyanine colorants

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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524 88, 528 60, 528 62, 540131, 540133, 540134, C08K 53472, C07D20956

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active

051772000

ABSTRACT:
A colorant for natural or synthetic resinous or polymeric materials, having the formula A--[SO.sub.2 --N(R.sub.2)--Y].sub.1-4 ; wherein: R.sub.2 is selected for example from hydrogen, methyl, cyclohexyl, phenyl or Y; A is a nonionic metallophthalocyanine chromophore which can be substituted for example with halogen, alkyl, alkoxy, alkylthio, or aryloxy; Y is a poly(oxyalkylene) moiety containing at least three monomeric units or mixtures thereof of the formula (--RO--) wherein each R is straight or branched alkylene of 2-4 carbons or mixtures thereof, up to about 20 mole percent of said monomeric units may be connected by one or more linking groups such as alkyleneoxy, --NH--, or --NHCONH--, and wherein Y can be terminated by hydrogen, or by at branch subsituents, containing 1-3 groups or moieties selected from alkyl, cycloalkyl, acyl, or aryl; wherein any of the above recited hydrocarbon groups, moieties or substituents may themselves be substituted with up to four substituents selected, for example, from alkyl, halogen, mercapto, alkoxycarbonyl, hydroxy, alkoxy, or the like; and wherein each aliphatic hydrocarbon portion or moiety of the groups, moieties or substituents recited above contains from 1-20 carbons.

REFERENCES:
patent: 2995412 (1961-08-01), Kleb
patent: 3287470 (1966-11-01), Pugin et al.
patent: 4284729 (1981-08-01), Cross et al.
patent: 4634555 (1987-01-01), Baxter et al.
patent: 4640690 (1987-02-01), Baumgartner et al.
Cooper, Spectroscopic Techniques for Organic Chemists, [New York, J. Wiley, 1980] pp. 240 to 243.
Texaco Corp. Jeffamine brochure, 1984.

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