Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...
Patent
1992-05-07
1994-12-20
Ivy, C. Warren
Organic compounds -- part of the class 532-570 series
Organic compounds
Heterocyclic carbon compounds containing a hetero ring...
C07D21136
Patent
active
053747291
ABSTRACT:
N-Methoxy derivatives of the sterically hindered amines 4-hydroxy-2,2,6,6-tetramethylpiperidine and 2,2,6,6-tetramethyl-4-piperidone are prepared from the corresponding N-oxyl hindered amine by combining hydrogen peroxide and a peroxide-decomposing transition metal salt in the presence of dimethyl sulfoxide.
REFERENCES:
patent: 4831134 (1989-05-01), Winter et al.
patent: 4921962 (1990-05-01), Galbo et al.
patent: 5004770 (1991-04-01), Cortolano et al.
patent: 5021481 (1991-06-01), Galbo et al.
patent: 5096950 (1992-03-01), Galbo et al.
patent: 5112890 (1992-05-01), Behrens et al.
Sholle et al., Interaction of the Nitroxide Radical with Grignard Reagent pp. 761-763 No Date Available.
Inst. J. Chem., 1982, 35, 2013-24.
J. Org. Chem. vol. 40, No. 23, 1975.
Chemical Communications, 1968 pp. 891-892.
Polymer Journal, vol. 6, No. 5, pp. 445-447 (1974).
C.A. 101:91124m (1984).
C.A. 76:25049e (1972).
Journal of Physical Chemistry, vol. 77, No. 10 (1973) pp. 1218-1221.
Huyser, Free-Radical Chain Reactions (1970) p. 287.
Scott, Atmospheric Oxidation and Antioxidatants (1965) pp. 77-79.
Dixon & Norman, Electron Spin Resonance Studies of Oxidation (1963) pp. 3119-3127.
Briere et al., Chimie Organique Physique du Centre d'Etudes Nucleaires Chemia des Martyrs (1965) pp. 3273-3283.
Bruni et al., Radicalic Methylation Unexpected Formation of Sulfones & Sulfonamides p. 74 (1968).
Ciba-Geigy Corporation
Covington Raymond
Hall Luther A. R.
Ivy C. Warren
Kovaleski Michele A.
LandOfFree
Process for preparing N-methoxy derivatives of 4-hydroxy-2,2,6,6 does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Process for preparing N-methoxy derivatives of 4-hydroxy-2,2,6,6, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for preparing N-methoxy derivatives of 4-hydroxy-2,2,6,6 will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-2386835