Phenylpropanals

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260600R, 252522, C07C 4752

Patent

active

041137817

ABSTRACT:
Substituted phenylpropanals and a process for their manufacture by reaction of the corresponding phenylethenes with carbon monoxide and hydrogen at temperatures of from 50.degree. to 180.degree. C and pressures of from 20 to 1,500 atmospheres gauge, in the presence of rhodium carbonyl complexes. The phenylpropanals according to the invention have pleasant scents. 3-(4-Isopropyl-phenyl)-butanal-1 and 3-(4-tert.-butyl-phenyl)-butanal-1, in particular, have suitable scents for the preparation of flower oil. They are also valuable starting materials for synthesizing drugs, plant protection agents and dyes.

REFERENCES:
patent: 2875131 (1959-02-01), Carpenter et al.
patent: 2880241 (1959-03-01), Hughes
patent: 3555098 (1971-01-01), Olivier et al.
patent: 3801646 (1974-04-01), Booth

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