Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1982-04-26
1984-02-14
Lone, Werren B.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
C07C 3700
Patent
active
044318480
ABSTRACT:
A process is disclosed for making resorcinol and substituted resorcinols by a first reaction step of vapor-phase cyclization of a delta-keto carboxylic acid ester over a carbon catalyst bed to form a 1,3-cyclic dione intermediate. The delta-keto ester is conveyed through the catalyst bed by a vaporized carrier characterized by being liquid at 25.degree. C. and having a sufficiently high boiling point that the vaporized carrier is easily condensable under ambient conditions. In a second reaction step, a liquid solvent containing the 1,3-cyclic dione intermediate is contacted with a supported noble-metal catalyst to form resorcinol or a substituted resorcinol.
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Keane J. Timothy
Koppers Company Inc.
Lone Werren B.
MacKay Donald M.
Zeh, Jr. Herbert J.
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