Preparation of resorcinol and substituted resorcinols by liquid-

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 3700

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active

044318480

ABSTRACT:
A process is disclosed for making resorcinol and substituted resorcinols by a first reaction step of vapor-phase cyclization of a delta-keto carboxylic acid ester over a carbon catalyst bed to form a 1,3-cyclic dione intermediate. The delta-keto ester is conveyed through the catalyst bed by a vaporized carrier characterized by being liquid at 25.degree. C. and having a sufficiently high boiling point that the vaporized carrier is easily condensable under ambient conditions. In a second reaction step, a liquid solvent containing the 1,3-cyclic dione intermediate is contacted with a supported noble-metal catalyst to form resorcinol or a substituted resorcinol.

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patent: 4160113 (1979-07-01), Muller et al.
patent: 4250336 (1981-02-01), Muller et al.

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