Melt oxychlorination process

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260654D, C07C 2100

Patent

active

041305957

ABSTRACT:
A melt oxychlorination process which produces trichloroethylene and perchloroethylene by chlorinating C.sub.2 hydrocarbons and their incompletely chlorinated derivatives containing at least 50% by weight of 1,1,2-trichloroethane, dichloroethylene, or both together, with a melt consisting essentially of iron chloride, copper chloride and alkali metal chloride by dispersing the material to be chlorinated in the melt whereby said material is chlorinated by the melt, wherein certain alkali metal chlorides, proportions thereof, and process conditions are utilized to provide desired product selectivity.

REFERENCES:
patent: 2140508 (1938-12-01), Reilly
patent: 2447323 (1948-08-01), Fontana
patent: 3222408 (1965-12-01), Smith
patent: 3363010 (1968-01-01), Schwarzenbek
patent: 3557229 (1971-01-01), Riegel
patent: 3671596 (1972-06-01), Bellis
patent: 3697608 (1972-10-01), Bellis

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