Production of unsaturated amines

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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252431N, 252431P, 2603268, 260563R, 260563C, 260563P, 260576, 260577, 260583H, 260583N, 260584R, 544178, 544404, 546184, C07C 8518

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041305906

ABSTRACT:
N-(alkadienyl)amines are produced at a rapid rate and in high yield by the reaction of conjugated dienes with ammonia and amines in a hydroxylic solvent using a catalyst system comprising a palladium compound co-catalyzed with a phosphonite ligand.

REFERENCES:
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patent: 3412158 (1968-11-01), McClain
patent: 3502725 (1970-03-01), Dewhirst et al.
patent: 3530187 (1970-09-01), Shryne
patent: 3819734 (1974-06-01), Kothart et al.
patent: 3891684 (1975-06-01), Jung
Mitsuyasu et al., "Chemical Communications (Japan)," p. 345 (1971).
Takahashi et al., "Bulletin of the Chemical Society of Japan," vol. 41, pp. 454-460 (1968).
Baker et al., "J. Chem. Soc., Perkin Trans 2," pp. 1511-1517 (1974).

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