Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1980-03-25
1981-12-22
Trousof, Natalie
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
260456R, 260463, 260941, 260946, 260950, 260957, 260960, 568346, 568347, 568591, 570216, 570218, C07C 67307, C07C 4148
Patent
active
043072437
ABSTRACT:
Conversion of esters (R.sup.1)(R.sup.2)C(C Hal.sub.3)OX, X being-P Hal.sub.2, --C(O)OR.sup.3 or ##STR1## R.sup.1, R.sup.3 and R.sup.4 being optionally substituted hydrocarbyl groups and R.sup.2 methyl or hydrogen, with zinc in acetic acid gives a very high yield of a dihalovinyl compound (R.sup.1)(R.sup.2)C.dbd.C Hal.sub.2, e.g., of the ethyl ester of the parent acid of pyrethroid insecticides.
REFERENCES:
patent: 4018838 (1977-04-01), Cleave
Stanley, J. Am. Chem. Soc., 81 pp. 1600-1602 (1959).
March, "Advanced Organic Chemistry", 2nd Ed., pp. 944-945 (1977).
Farkas, Coll. Czech. Chem. Commun., 24 pp. 2230-2236 (1959).
Kramer Petrus A.
Verbrugge Pieter A.
Shell Oil Company
Shippen Michael
Trousof Natalie
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