Preparation of esters

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C12000, C07C12175

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active

042997763

ABSTRACT:
.alpha.-cyano esters are prepared by reacting an acyl halide with an aldehyde in a homogeneous mixture of substantially water-miscible aprotic solvent and an aqueous solution of water-soluble cyanide salt.

REFERENCES:
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patent: 3835176 (1974-09-01), Matsuo et al.
patent: 4024163 (1977-05-01), Elliott et al.
patent: 4113763 (1978-09-01), Norton
patent: 4123451 (1978-10-01), Sheldon et al.
Francis et al., J. Chem. Soc., 95, 1403 (1909).
Loudon et al., J. Chem. Soc., PT.2, 1780 (1959).
Zymalkowski et al., Arch. Pharm., 290, 218 (1957).

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