Fl Polyesters

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528 70, 560193, 560197, C08G 6368

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active

044827024

ABSTRACT:
Fluorinated prepolymers prepared by non-stoichiometrically reacting an alcohol having at least alcoholic carbons and at least one trifluoromethylene group attached to each alcoholic carbon with a fluorinated polycarboxylic acid having at least one methylene group between each carboxyl group and each fluorinated carbon. The reaction is carried out neat while the reactants are in liquid form and typically in a flowing, non-reactive atmosphere.

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patent: 4379912 (1983-04-01), Lu
Schweiker et al., "Condensation Polymers Containing Fluorine I. Synthesis Linear Polyesters from Fluorine-Containing Diols", J. Pol. Sci. vol. XXIV, pp. 33-41 (1957).
Wall, ed., High Polymers, vol. 25, "Fluoropolymers", pp. 202-203, 213-215, Wiley-Interscience, N.Y. (1972).
Filler, et al., "Fluorinated Esters, III., Diesters of Carboxylic Acids with Fluorine-containing Alcohols and Glycols", J.A.C.S. vol. 75, pp. 2693-2695 (1953).
Faurote et al., "Catalyst for Promoting Direct Esterification of Fluoroalcohols", Indus. and Eng. Chem., vol. 49, No. 2 (1957).

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