Disproportionation of amines to produce secondary amines

Details Disproportionation of amines to produce secondary amines Disproportionation of amines to produce secondary amines

1995-02-21

1996-10-22

Burn, Brian M.

Organic compounds -- part of the class 532-570 series

Organic compounds

Amino nitrogen containing

564470, C07C20964

Patent

active

055678475

ABSTRACT:
This invention relates to an improvement in a process for the production of amines and particularly secondary amines by the hydrogenation of aliphatic and aromatic nitriles and disproportionation of the resulting primary amine containing feedstock. The improvement resides in the use of a bimetallic catalyst comprising nickel or cobalt in combination with rhodium, ruthenium or palladium platinum. Optionally, the catalyst is carried on an alumina support.

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Volf, Jiri and Josef Pasek, Prague Institute of Chemical Technology "Hydrogenation of Nitriles" Studies in Surface Science & Catalysis, vol. 27 pp. 105-144 1986.

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