Promoters in the polymerization of monovinyl-aromatic compounds

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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Other Related Categories

260878B, 260879, C08F 1208, C08F 1212

Type

Patent

Status

active

Patent number

040888134

Description

ABSTRACT:
1,1-DIALKYLETHYLENES, SUCH AS ISOBUTENE, PROMOTE THE PRIMARY LITHIUM INITIATED POLYMERIZATION OF MONOVINYL-AROMATIC COMPOUNDS, SUCH AS STYRENE, EITHER IN HOMOPOLYMERIZATIONS, OR IN THE FORMATION OF A--B--A block copolymers or (A--B).sub.a Z radial block copolymers, such as by sequential monomer addition with conjugated dienes.

REFERENCES:
patent: 2802806 (1957-08-01), Doak
patent: 3030346 (1962-04-01), Cooper
patent: 3031432 (1962-04-01), Kern
patent: 3551522 (1970-12-01), Miles
patent: 3631006 (1971-12-01), Hawkins
patent: 3992483 (1976-11-01), Willis
patent: 3993853 (1976-11-01), Selman et al.
Org. Chem. of Syn. High Polymers by Lenz, pp. 412-413; Interscience Pub. 1967.

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