Cis and trans-6-substituted-11-aminoalkylidene-5,6-dihydromorpha

Details Cis and trans-6-substituted-11-aminoalkylidene-5,6-dihydromorpha Cis and trans-6-substituted-11-aminoalkylidene-5,6-dihydromorpha

1973-12-06

1976-01-06

Demers, Arthur P.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260239D, 424244, C07D22318

Patent

active

039311589

ABSTRACT:
Pure cis and trans-6-substituted-11-aminoalkylidene-5,6-dihydromorphanthridines are prepared by treating the morphanthridines unsubstituted in the 6-position with a Grignard reagent in a suitable solvent such as tetrahydrofuran. Among the compounds disclosed are:

REFERENCES:
patent: 3699099 (1972-10-01), Drukker
Kharasch et al., Grignard Reactions of Non-Metallic Substances, Prentice-Hall, N.Y., N.Y., 1954, p. 1204.
Nesmayanov et al., Methods of Elemento-Organic Chemistry, North-Holland Publishing Co., Amsterdam, 1967, p. 608.

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