Oligomeric oxolanyl alkanes as modifiers for polymerization of d

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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502157, C08F 448

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active

044290918

ABSTRACT:
A process and catalyst system is disclosed herein for the preparation of (co)polymers having a 1,2-microstructure of between 20 and 95 percent. These (co)polymers are prepared in a hydrocarbon or other non-polar solvent from a monomer system which contains at least one 1,3-diene monomer. The catalyst system which is employed in the production of the (co)polymers of the present invention is a combination of (1) an anionic initiator based on lithium, and (2) a modifier compound selected from the group consisting of linear and cyclic oligomeric oxolanyl alkanes.

REFERENCES:
patent: 3726832 (1973-04-01), Komatsu

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