Process for the preparation of esters of alpha-ethylenically uns

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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C07C 6736

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active

048311871

ABSTRACT:
A process for preparing esters of alpha-ethylenically unsaturated alcohols and alpha-ethylenically unsaturated carboxylic acids by reacting an acetylenically unsaturated compound with CO and a ketone containing a group HC--C(.dbd.O), using a Pd(II) catalyst, a triphenylphosphine in which the phenyl groups carry an electron-withdrawing substituent and a non-carboxylic protonic acid having a pK.sub.a not greater than 1.5.

REFERENCES:
patent: 3859319 (1975-01-01), Mrowca
patent: 3904672 (1975-09-01), Knifton
patent: 4055721 (1977-10-01), Kawata et al.
patent: 4480121 (1984-10-01), Klun et al.

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