Chemical process involving ethers and amines

Details Chemical process involving ethers and amines Chemical process involving ethers and amines

1986-06-20

1988-03-08

Hollrah, Glennon H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Nitriles

558408, 564152, 564157, 564164, 564168, 564194, 564197, 564343, 564396, 564446, 564471, 560 37, 560 43, 560125, 560155, C07C 8518, C07C10200, C07C12000, C07C10100

Patent

active

047300752

ABSTRACT:
A process for the production of (1) an ether or (2) a second amine comprises reacting an activated olefin with respectively an alcohol or first amine in the presence of a catalyst which is either (a) an amidine or (b) a Lewis base and epoxide. The same catalyst may also be used to carry out the reverse reaction in which an activated olefin and an alcohol or first amine are produced from the appropriate ether or second amine.

REFERENCES:
patent: 4617154 (1986-10-01), Green
Fieser et al., Reagents for Organic Synthesis, vol. 4, pp. 16-18 (1974).

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