Methods and reagents for enhancing the cycling efficiency of lit

Chemistry: electrical current producing apparatus – product – and – Fluid active material or two-fluid electrolyte combination...

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429105, 4292319, 42923195, 429303, 429314, 429319, H01M 436

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060176512

ABSTRACT:
Batteries including a lithium electrode and a sulfur counter electrode that demonstrate improved cycling efficiencies are described. In one embodiment, an electrochemical cell having a lithium electrode and a sulfur electrode including at least one of elemental sulfur, lithium sulfide, and a lithium polysulfide is provided. The lithium electrode includes a surface coating that is effective to increase the cycling efficiency of said electrochemical cell. In a more particular embodiment, the lithium electrode is in an electrolyte solution, and, more particularly, an electrolyte solution including either elemental sulfur, a sulfide, or a polysulfide. In another embodiment, the coating is formed after the lithium electrode is contacted with the electrolyte. In a more particular embodiment, the coating is formed by a reaction between the lithium metal of the lithium electrode and a chemical species present in the electrolyte.

REFERENCES:
patent: 3404035 (1968-10-01), Kummer et al.
patent: 3413150 (1968-11-01), Kummer et al.
patent: 3532543 (1970-10-01), Nole et al.
patent: 3907591 (1975-09-01), Lauck
patent: 3915743 (1975-10-01), Lauck
patent: 3953231 (1976-04-01), Farrington et al.
patent: 4143214 (1979-03-01), Chang
patent: 4154902 (1979-05-01), Schwartz
patent: 4218523 (1980-08-01), Kalnoki-Kis
patent: 4268587 (1981-05-01), Farrington et al.
patent: 4331743 (1982-05-01), Dey et al.
patent: 4410609 (1983-10-01), Peled et al.
patent: 4469761 (1984-09-01), Bennett et al.
patent: 4644911 (1987-02-01), Perichaud et al.
patent: 4780380 (1988-10-01), Prafer
patent: 4833048 (1989-05-01), Dejonghe et al.
patent: 4869977 (1989-09-01), Connolly et al.
patent: 4917974 (1990-04-01), De Jonghe et al.
patent: 5162175 (1992-11-01), Visco et al.
patent: 5512386 (1996-04-01), Simon
patent: 5523179 (1996-06-01), Chu
patent: 5529860 (1996-06-01), Skotheim et al.
patent: 5532077 (1996-07-01), Chu
patent: 5582623 (1996-12-01), Chu
patent: 5686201 (1997-11-01), Chu
Abstract of proceedings of the 6th International Symposium on Power Sources 2, 1968, Brighton, Sussex, UK, Sep. 24-26, 1968, no month available.
Coleman et al., "The Sulfur Electrode" proceedings of the 6th International Symposium on Power Sources, pp. 289-302 (1968).
Visco, S.J., Liu, M., Armand, B. and De Jonghe, L.C., Solid Redox Polymerization Electrodes and Their use in All-Solid-State Batteries, Mol. Cryst. Liq. Cryst., 190, p. 198, 1990, no month available.
Societe des Accumulateurs Fixes et de Traction, "Lithium-sulfur battery" Abstracts 111055d, Chemical Abstracts 66: 10360; 1967, no month available.
DeGott, P., "Polymere Carbone-Soufre Synthese Et Proprietes Electrochimiques," Doctoral Thesis as l'Institut National Polytechnique de Grenoble, (Date of Defense Jun. 19, 1986).
Lauck, H., "Storage battery with lithium anode and sulfur cathode," Abstract #9855s, Chemical Abstracts, 80:467-468; 1974, no month available.
Peled et al., Rechargeable Lithium-Sulfur Battery (Extended Abstact), Journal of Power Source, 26: 269-271, 1989, no month available.
Peled et al.; "Lithium-Sulfur Battery: Evaluation of Dioxolane-Based Electrolytes", J. Electrochem., Soc., 136(6): 1621-1624, Jun. 1989.
Peramunage and Licht, "A Solid Sulfur Cathode for Aqueous Batteries"; Science 261: 1029-1032, Aug. 20, 1993.
Rauh et al., "Formation of Lithium Polysulfides in Aprotic Media", J. Inorg., Nuc. Chem., 39: 1761-1765, 1977, no month available.
Rauh et al. "A Lithium/Dissolved Sulfur Battery with an Organic Electrolyte"; J. Electrochem. Soc., 126(4): 523-527, Apr. 1979.
Yamin and Peled, "Electrochemistry of Nonaqueous Lithium/Sulfur Cell", J. Power Sources, 9: 281-287, 1983, no month available.
Yamin et al., Lithium Sulfur Battery,: J. Electrochem. Soc., 135(5): 1045-1048, May 1988.
S.J. Visco, M.M. Doeff, and L.C. De Jonghe, "Thin-Film Technology for Solid-State Lithium Batteries Employing Solid Redox Poly-Merization Cathodes", pp. 89-92, Society of Vacuum Coaters, 1991, no month available.
Liu, Meilin, Visco, Steven J., and De Jonghe, Lutgard C., "Novel Solid Redox Polymerization Electrodes Electrochemical Properties", J. Electrochem Soc., vol. 138, No. 7, pp. 1896-1901, Jul 1991.
Liu, Meilin, Visco, Steven J., and De Jonghe, Lutgard C., "Novel Solid Redox Polymerization Electrodes All-Solid State, Thin-Film, Rechargeable Lithium Batteries", J. Electrochem Soc., vol. 138, No. 7, pp. 1891-1895, Jul. 1991.
Ue, Makoto, Visco, Steven J., and De Jonghe, Lutgard C., "Compariso of Cathode Utilization between Polymeric Organodisulfide and Titanium Disulfide in Solid Polymer Electrode Rechargeable Lithium Cells", Denki Kagaku, vol. 61, No. 12, pp. 1409-1415, 1993, no month available.
Meilin, Lui, "Novel Electrodes for Advanced Energy Storage System" Dissertation for Ph.D. at the University of Berkeley, Chapter 2, pp. 3-6, 1989, no month available.
J.R. Coleman, et al., "The Sulfur Electrode", (1968) 289-302, Defense Chemical Biological and Radiation Establishment, Defense Research Board, Ottawa, Canada, no month available.
R.D. Rauh et al., Rechargeability Studies of Ambient Temperature Lithium/Sulfur Batteries, EIC Corporation, 55 Chapel Street, Newton, MA 02158, no month available.
D. Nole, et al., "Battery Employing Lithium-Sulphur Electrodes with Non-Aqueous Electrolyte", U.S. Patent 3,532,543 (1970), no month available.
E. Peled, et al. "Lithium-Sulfur Battery: Evaluation of Dioxolane Based Electrodes", J. Electrochemical Society, 136, 1621-1624 (1989), no month available.
A. Yamin, et al. "Electrochemistry of a Nonaqueous Lithium/Sulfur Cell", J. Power Sources, 9, 281-287 (1983), no month available.
H. Yamin, et al. "Lithium Sulfur Battery--Oxidation/Reduction Mechanisms of Polysulfides in THF Solutions", J. Electrochemical Society,135, 1045-104 (1988), no month available.
S.B. Brummer, et al. "Low Temperature Lithium/Sulfur Secondary Battery", U.S. Energy Research and Development Administration Div. of Electric Energy Systems, 1-57 (1976), no month available.
E. Peled, et al. "Rechargeable Lithium-Sulfur Battery (Extended Abstract)", J. Power Sources, 26, 269-271 (1989), no month available.
Peled, et al. "Electrochemical Cell", U.S. Patent 4,410,609 (1983), no month available.
R.D. Rauh, et al. "Formation of Lithium Polysulfides in Aprotic Media", J. Inorg. Nuc. Chem., 39, 1761-1765 1977).
R.D. Rauh, et al. "A Lithium/Dissolved Sulfur Battery with an Organic Electrolyte", J. Electrochemical Society, 126, 523-527 91979), no month available.
R.D. Rauh, et al. "Rechargeability Studies of Ambient Temperature Lithium/Sulfur Batteries", 12th IECEC, 283-287 (1977).
A. Gavrilov, et al. "In Situ Morphological Study of Lithium-Electrolyte Interface", Electrochemical Society, (Extended Abstract), no month available.
Kavan, L., Novak, P., and Dousek, F.P., "Electrochimica Acto," vol. 33, No. 11, pp. 1605-1612, Mar. 8, 1988, Great Britain.
Brummer, S.B., et al., "Low Temperature Lithium/Sulfur Secondary Battery (Annual Progress Report, Dec. 1, 1974 -Dec. 1, 1975)," EIC Corporation, Apr. 1976, Newton, Massachusetts.
Larry A. Dominey, "Lithium Batteries" New Materials, Developments and Perspectives, 1994, New York, Industrial Chemistry Library, vol. 5, pp. 137-165, no month available.
Ronald Snaith, et al., "Lithium Chemistry" A Theoretical and Experimental Overview, 1995, New York, John Wiley & Sons, Inc., pp. 227-477, No month available.

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