Process and means for the oxidative destruction of azides

Hazardous or toxic waste destruction or containment – Containment

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588203, 423410, 210753, 210903, A62D 300

Patent

active

054572657

ABSTRACT:
The invention relates to a process and means for the oxidative destruction of azides. The process is characterized in that the azide-containing solutions to be disposed of are treated with an iodine solution in the presence of an iodide and a thiosulfate. The means are preferably employed in the form of tablets.

REFERENCES:
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patent: 5073273 (1991-12-01), Gupta et al.
Mellor, J. W. A Comprehensive Theatise on inorganic & theoretical Chemistry, Longsman Green & Co. New York, NY 1949 vol. VIII p. 317.
Fundamentals of Analytical Chemistry, 1969, Skoog, p. 434.
Holleman-Wiberg "Lehrbuch der Anorganischen Chemie", Berlin-New York 1985, pp. 568-570.
Chemical Abstracts, vol. III, No. 26, 239274g.
Browning, Jon E. Chemical Engineering "Tableting" Dec. 4, 1967 pp. 151-170.
Summerville, et al. Clinical Chemistry "Iodine-Azide Spot Test. . . " vol. 28 No. 4, 1982 pp. 717-718.
Jirousek, Ludek Analytical Biochemistry "On the Reaction of Sulfenyl Iodide Denv. w/Azide" 1974(61), pp. 434-440.
Armour et al., "Safety in the Chemical Laboratory", J. Chem. Educ. 62 vol. 62, No. 3, A93 (03/85).

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