Polyphthalocyanines prepared from N,N-bis(3,4-dicyanophenyl) alk

Details Polyphthalocyanines prepared from N,N-bis(3,4-dicyanophenyl) alk Polyphthalocyanines prepared from N,N-bis(3,4-dicyanophenyl) alk

1974-08-23

1976-11-23

Lee, Lester L.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

260 7841, 260465D, 428474, C08G 7306

Patent

active

039936317

ABSTRACT:
N,N'-bis(3,4-dicyanophenyl) alkanediamides of the general formula: ##SPC1##
Wherein R = (CH.sub.2).sub.n.sub.-2 and (CH.sub.2).sub.x CH(CH.sub.3)(CH.sub. 2).sub.y ; n = 3 to 20; x = 1 to 8; and y = 1 to 8, prepared by reacting 4-aminophthalonitrile with a saturated aliphatic dicarboxylic acid halide. These dinitriles readily polymerize through heating by themselves or with a metal or with a salt to form polyphthalocyanine resins, of the infinite molecular weight type which are useful as coatings, laminates, adhesives, filament windings, and castings. The general formulas for these polyphthalocyanine resins are: ##SPC2## ##SPC3##
Wherein R = (CH.sub.2).sub.n.sub.-2 and (CH.sub.2).sub.x CH(CH.sub.3)(CH.sub.2).sub.y ; n = 3 to 20; x = 1 to 8; and y = 1 to 8.

REFERENCES:
patent: 3245965 (1966-04-01), Tuemmler
patent: 3654192 (1972-04-01), Vogel
patent: 3775380 (1973-11-01), Miller
patent: 3826783 (1974-07-01), Bloch
patent: 3836506 (1974-09-01), Frost
patent: 3864309 (1975-02-01), Bilow et al.
griffith and Walton, "Resin Systems Cured Through Aromatic Ortho Dinitrile roup " Coatings and Plastics, Preprints, 34, No. 1,784 (4/74).
Griffith and Walton, "Resin Systems Cured Through Aromatic Ortho Dinitrile Group", Polymer Preprints 15, No. 1, 787-790 (4/74).

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