Carbamate modified sulfonated and non-sulfonated hydroxy-functio

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Compositions to be polymerized by wave energy wherein said...

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522 81, 522174, 522182, 522183, 525455, 4284259, 428694, 428900, C08F 250, C08F 7104, C08F29300, B32B 2700

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active

052409724

ABSTRACT:
The present invention relates to an iniferter compound of the formula I(T).sub.n wherein I represents the free radical initiator portion of the iniferter compound and wherein I comprises a hydroxy-functional polyurethane polymer which comprises: (i) a polyurethane backbone; (ii) a plurality of cross-linkable hydroxy groups pendant from the polyurethane backbone, wherein the polyurethane backbone has a hydroxy equivalent weight of from about 500 to about 10,000; (iii) at least n organic groups X which can be the same or different pendant from the polyurethane backbone wherein each organic group X is also bonded to a T group; T represents the terminator portion of the iniferter; and n is an integer of at least 1; wherein T and X are organic groups selected so that the T--X bond is capable of dissociating upon being subjected to an appropriate energy source of forming a terminator free radical of the formula nT.multidot. and an initiator free radical of the formula I(.multidot.).sub.n . The invention also relates to an iniferter which further comprises at least one SO.sub.3 M group pendant from the polyurethane backbone, to vinyl/polyurethane copolymers made from the iniferters, to a method of making the copolymers, and to the use of the copolymers in magnetic recording media.

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