Method of an apparatus for forming thin film for semiconductor d

Coating apparatus – Gas or vapor deposition – Multizone chamber

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118715, 118724, 118725, C23C 1600

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052405052

ABSTRACT:
A method of forming a thin film for a semiconductor device, for forming a metal thin film by chemical vapor deposition on an intermediate layer which is provided on a substrate, comprises the steps of activating the surface of the intermediate layer by introducing a halide gas of a metal for forming the thin film onto the surface of the intermediate layer, forming nuclei on the surface of the intermediate layer by introducing a silane-system gas onto the activated surface of the intermediate layer, and introducing the halide gas and a reducing gas onto the surface of the intermediate layer formed with the nuclei, thereby depositing the metal thin film on the surface of the intermediate layer.

REFERENCES:
patent: 3969779 (1972-10-01), Murai
patent: 4505949 (1985-03-01), Jelks
patent: 4592306 (1986-06-01), Gallego
patent: 4615298 (1986-10-01), Yamazaki
patent: 4825808 (1989-05-01), Takahashi
patent: 4969415 (1990-11-01), Bartha
patent: 4976996 (1990-12-01), Mankowski
"A Mechanism for Selectivity Loss During Tungsten CVD" by J. R. Creighton, "J. Electrochemical Society", vol. 136, No. 1, pp. 271-275, Jan. 1989.

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