Copolymers of L-(-)-lactide and epsilon caprolactone

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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C08G 6308

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active

040575373

ABSTRACT:
Copolymers which can be fabricated into films, fibers and structural shapes are prepared by copolymerizing an optically active lactide, i.e., L-(-)-lactide, and epsilon caprolactone in the presence of a tin ester of a carboxylic acid. A copolymer prepared from 75 parts by weight of L-(-)-lactide and 25 parts by weight of epsilon caprolactone is a thermoplastic elastomer. A copolymer prepared from 90 parts by weight of L-(-)-lactide and 10 parts by weight of epsilon caprolactone is a rigid, clear, thermoplastic solid.

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patent: 3636956 (1972-01-01), Schneider
patent: 3736646 (1973-06-01), Schmitt et al.
patent: 3839297 (1974-10-01), Wassermann et al.

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