Chemistry of hydrocarbon compounds – Purification – separation – or recovery – By addition of extraneous agent – e.g. – solvent – etc.
Patent
1979-10-26
1980-12-02
Davis, C.
Chemistry of hydrocarbon compounds
Purification, separation, or recovery
By addition of extraneous agent, e.g., solvent, etc.
260597A, 585850, C07C 7152
Patent
active
042373310
ABSTRACT:
Olefins are oxidized to carbonyl compounds, for example, 2-hexene to a mixture of 2-hexanone and 3-hexanone, with a palladium/copper/boric acid catalyst and a suitable surfactant or phase transfer agent. The reaction takes place in a diluent system comprising at least two liquid phases, wherein at least one liquid phase is an aqueous phase, and in the presence of free oxygen. The catalyst system can be used to oxidize internal olefins, as well as terminal olefins, at reasonable rates. The catalyst system can also be used for the selective oxidation of linear olefins in a mixed stream containing linear and branched olefins.
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Chem. Abs. 83, 178203v (1975).
Encyclopedia of Chemical Technology, Kirk-Othmer, vol. 3, (1964), pp. 830-865.
Davis C.
Phillips Petroleum Company
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