Selective hydrogenation of certain nitroaromatic hydroxy substit

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

260571, 260575, 260580, 260578, C07C 7922, C07C 8511, C07C 8524

Patent

active

042163412

ABSTRACT:
Nitroaromatic hydroxy substituted acetylene compounds wherein both the nitro and acetylene groups are directly connected to aromatic ring carbon atoms are hydrogenated in an inert solvent to selectively reduce the nitro function over a ruthenium disulfide catalyst. Of particular interest is the preparation of aminophenylacetylene from nitrophenyl hydroxy substituted acetylene.

REFERENCES:
patent: 2402684 (1946-06-01), Signaigo
patent: 3118946 (1964-01-01), Grob et al.
patent: 3350450 (1967-10-01), Dovell et al.
patent: 3845018 (0000-01-01), Bilow et al.
patent: 3879349 (1977-04-01), Billow et al.
patent: 3907968 (1975-09-01), Kobylinski et al.
patent: 4051177 (1977-09-01), Braden et al.
Burawoy et al., "Tetrahedron", (1959), vol. 5, pp. 340-351.
Friefelder, "Practical Catalytic Hydrogenation", p. 168 (1971), Wiley.
Hennion, "J. Amer. Chem. Soc.", vol. 79 pp. 2146-2148.
Huntress, "J. Amer. Chem. Soc.", vol. 56, p. 241, (1934).
Organic Syntheses, Coll. vol. 3, pp. 69-70.
Woodburn et al., "J. Amer. Chem. Soc.", vol. 72, p. 1361.
Chem. Abs., vol. 79 (1973), p. 77771r: Chem. Abs., vol. 81 (1974), p. 151684z.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Selective hydrogenation of certain nitroaromatic hydroxy substit does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Selective hydrogenation of certain nitroaromatic hydroxy substit, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Selective hydrogenation of certain nitroaromatic hydroxy substit will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-2281475

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.