Preparation of alkane diamines

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260566R, 260566A, 260566P, 260583M, 260583P, 260593A, C07C 8508

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active

041599969

ABSTRACT:
A method for preparing alkane diamines by initially reacting a vicinal nitroketone with a primary amine hydrochloride thereby forming a nitroalkyliminoalkane or a nitrooximinoalkane and thereafter catalytically hydrogenating the nitroalkylimino- or nitrooximinoalkane to a diamine.

REFERENCES:
patent: 1799110 (1931-03-01), Manske
patent: 2746959 (1956-05-01), Bruce et al.
patent: 3737462 (1973-06-01), Cheema et al.
patent: 3772358 (1973-11-01), Billere
Beilsteine, "Organischen Chemie", vol. 1, Acyclische Reihe, p. 661 (1918).
Wagner et al., "Synthetic Organic Chemistry", p. 728 (1953).

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