Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Carbon dioxide or hydrogen sulfide component
Patent
1979-12-21
1981-02-17
Thomas, Earl C.
Chemistry of inorganic compounds
Modifying or removing component of normally gaseous mixture
Carbon dioxide or hydrogen sulfide component
423232, 423234, B01D 5334
Patent
active
042514940
ABSTRACT:
An improved process for removing carbon dioxide from a gaseous feed including carbon dioxide is described. The carbon dioxide is removed from a gaseous feed by contacting the feed in a contacting zone with a scrubbing solution comprising a sterically hindered amine and an alkali metal salt or alkali metal hydroxide, which at least partially absorbs the carbon dioxide. The scrubbing solution subsequently is desorbed and separated into a two-phase liquid system, an upper phase relatively rich in sterically hindered amine and having a relatively high ratio of alkali bicarbonate to alkali carbonate and a lower liquid phase having a relatively low ratio of alkali bicarbonate to alkali carbonate. The lower liquid phase is returned to the contacting zone at a location above that at which the upper liquid phase is returned to the contacting zone.
REFERENCES:
patent: 2886405 (1959-05-01), Benson et al.
patent: 4094957 (1978-06-01), Sartori et al.
patent: 4112050 (1978-09-01), Sartori et al.
patent: 4112051 (1978-09-01), Sartori et al.
patent: 4112502 (1978-09-01), Sartori et al.
Exxon Research & Engineering Co.
Mazer Edward H.
Thomas Earl C.
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