Preparation of tertiary butyl alcohol by catalytic decomposition

Details Preparation of tertiary butyl alcohol by catalytic decomposition Preparation of tertiary butyl alcohol by catalytic decomposition

1993-11-12

1995-03-28

Evans, Joseph E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568922, C07C 2900, C07C 3112, C07C 2988

Patent

active

054018897

ABSTRACT:
A method for preparing tertiary butyl alcohol wherein a feedstock comprising a solution of tertiary butyl hydroperoxide in a cosolvent mixture of tertiary butyl alcohol with isobutane is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst and is brought into contact with the catalyst in liquid phase with agitation under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol.

REFERENCES:
patent: 3505360 (1970-04-01), Allison et al.
patent: 3591656 (1971-07-01), Krell
patent: 3915893 (1975-10-01), Flanigen et al.
patent: 4910349 (1990-03-01), Sanderson et al.
patent: 5243101 (1993-09-01), Sanderson et al.

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