Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1996-11-22
1998-03-03
Shaver, Paul F.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
568607, 568609, 568659, 568660, 568662, 568626, C07C 3700
Patent
active
057236941
ABSTRACT:
Phenols monomethylated or dimethylated in the ortho or para position to the OH group and having the formula ##STR1## can be prepared by reaction of tert-alkyl-substituted phenols of the formula ##STR2## in which at least one free ortho or para position to the OH group is present, in three reaction steps a), b) and c). In a), (II) is reacted with formaldehyde or its polymers and a carboxylic acid of the formula
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K-D. Bode, V. Herstellung von Phenolen bzw. Phenol-Derivaten aus anderen Phenolen unter Erhaltung der phenolischen Funktion, Methoden der Organischen Chemie (Houben-Weyl), Band VI/lc, p. 925, (1976).
B. Delmon, et al., Zeolites as Catalysts, Sorbents and Detergent Builders Applications and Innovations, Studies in Surface Science and Catalysis, vol. 46, pp. 168-179, (1989).
H. Fiege, Ullmann's Encyclopedia of Industrial Chemistry, Fifth, Completely Revised Edition, Cresols and Xylenols, vol. A 8, p. 25 (1975).
Botta Artur
Buysch Hans-Josef
Bayer Aktiengesellschaft
Shaver Paul F.
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