Process for preparing monomethylated or dimethylated phenols

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568607, 568609, 568659, 568660, 568662, 568626, C07C 3700

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057236941

ABSTRACT:
Phenols monomethylated or dimethylated in the ortho or para position to the OH group and having the formula ##STR1## can be prepared by reaction of tert-alkyl-substituted phenols of the formula ##STR2## in which at least one free ortho or para position to the OH group is present, in three reaction steps a), b) and c). In a), (II) is reacted with formaldehyde or its polymers and a carboxylic acid of the formula

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K-D. Bode, V. Herstellung von Phenolen bzw. Phenol-Derivaten aus anderen Phenolen unter Erhaltung der phenolischen Funktion, Methoden der Organischen Chemie (Houben-Weyl), Band VI/lc, p. 925, (1976).
B. Delmon, et al., Zeolites as Catalysts, Sorbents and Detergent Builders Applications and Innovations, Studies in Surface Science and Catalysis, vol. 46, pp. 168-179, (1989).
H. Fiege, Ullmann's Encyclopedia of Industrial Chemistry, Fifth, Completely Revised Edition, Cresols and Xylenols, vol. A 8, p. 25 (1975).

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