Pressure-sensitive adhesives for marking films

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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524460, 523201, C09J15104, C09J15100

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active

058958010

ABSTRACT:
Inherently tacky polymerized copolymer particles are formed by emulsion polymerization for use as an PSA for marking films. The adhesives are the reaction product formed by emulsion polymerization of a first monomer mixture comprising at least one alkyl acrylate containing from 4 to about 12 carbon atoms in the alkyl group, at least one hard monomer, and at least one unsaturated carboxylic acid containing from 3 to about 5 carbon atoms and present in a total amount of from about 3 to about 6% by weight of the first monomers which there is added by the reaction product of a second monomer system comprising at least one alkyl acrylate containing from 4 to about 12 carbon atoms in at least one unsaturated carboxylic acid monomer present containing from 3 to about 5 carbon atoms in present in a total amount from about 7 to about 10% by weight of the monomers, said second copolymer being substantially free of other hard monomers in which said first copolymer is present in an amount at least 50% by weight of the total copolymers and has a glass transition temperature from 0 to about -25.degree. C. The second copolymer has a glass transition temperature of from about -25.degree. C. The copolymers are preferentially formed by sequential polymerization.

REFERENCES:
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patent: 4948822 (1990-08-01), Iovine
patent: 5129126 (1992-07-01), Huang
patent: 5164444 (1992-11-01), Bernard
patent: 5264532 (1993-11-01), Bernard
patent: 5278227 (1994-01-01), Bernard
patent: 5405879 (1995-04-01), Uemae
patent: 5550181 (1996-08-01), Scholz
English-language translation of Japanese Patent No. 264,077 (Nov. 1986).

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