Process for the preparation of 5-mercapto-1,2,3-triazoles

Details Process for the preparation of 5-mercapto-1,2,3-triazoles Process for the preparation of 5-mercapto-1,2,3-triazoles

1979-11-21

1981-03-31

Rollins, Alton D.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

548127, C07D24904

Patent

active

042595029

ABSTRACT:
A process for the preparation of compound of the general formula ##STR1## described, in which a compound of formula ##STR2## is reacted with alcohol or phenol of formula ##STR3## in an organic solvent to form a compound of formula ##STR4## which is converted by acid or base catalyzed reaction to form a compound of formula ##STR5## which is then rearranged in the presence of base to form the desired product.

REFERENCES:
patent: 4012382 (1977-03-01), Bouzard et al.
Goerdeler et al., Ber. Deut. Chem. Ges., vol. 99, pp. 1618-1631 (1966).
Smith, Open-chain Nitrogen Compounds, (W. A. Benjamin, Inc., New York, 1965), Vol. 1, pp. 71-72.
Smith, Open-chain Nitrogen Compounds, (W. A. Benjamin, Inc., New York, 1965), vol. 2, p. 219.
Wagner et al., Synthetic Organic Chemistry, (New York, 1953), p. 575.
Theilheimer, Synthetic Methods of Organic Chemistry, vol. 17, (New York, 1963), p. 215.

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