Process for the preparation of nitroolefins

Details Process for the preparation of nitroolefins Process for the preparation of nitroolefins

1988-07-15

1989-08-29

Terapane, John F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568943, 568924, C07C 7908

Patent

active

048619256

ABSTRACT:
A process for the preparation of nitroolefins which comprises heating a solution of a nitroalcohol of the formula: ##STR1## to at least 125.degree. C. to give a corresponding nitroolefin which is contacted in situ with nucleophilic addition reagent.

REFERENCES:
patent: 2414594 (1947-01-01), Gold
patent: 3240823 (1966-03-01), Bonetti et al.
patent: 3255263 (1966-06-01), Abbott
patent: 3510531 (1970-05-01), Larkin et al.
patent: 4384149 (1983-05-01), Suzuki
Nitration of Hydrocarbons A. V. Topchiev, Pergamon Press, New York, 1959, pp. 193-199.
Unsaturated Nitro Compounds, V. V. Perekalin, Daniel Davey & Co., Inc., New York, 1964, pp. 15-31.

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