Catalytic process for manufacturing alcohols by hydrogenolysis o

Details Catalytic process for manufacturing alcohols by hydrogenolysis o Catalytic process for manufacturing alcohols by hydrogenolysis o

1983-05-24

1984-06-26

Evans, J. E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

502242, 502261, 502332, C07C 29136

Patent

active

044567758

ABSTRACT:
Alcohols and particularly fatty alcohols are manufactured by hydrogenolysis of carboxylic esters in the presence of a catalyst comprising a carrier, rhodium and at least one second element selected from the group consisting of tin, germanium and lead. The rhodium content is from 0.1 to 5% b.w. and the content of the second element is from 0.1 to 10% b.w.

REFERENCES:
patent: 2322095 (1943-06-01), Schmidt
patent: 3769331 (1973-10-01), Kuckertz et al.
patent: 3829448 (1974-08-01), Kanetaka et al.
patent: 4104478 (1978-08-01), Triredi
patent: 4273947 (1981-06-01), Novotny
patent: 4338221 (1982-07-01), Qualeatti
Grimm et al., "J. Am. Oil Chemists Soc.", vol. 46, No. 2, p. 118, (1968).

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