Production of acetamides with rhodium-manganese catalysts

Details Production of acetamides with rhodium-manganese catalysts Production of acetamides with rhodium-manganese catalysts

1979-12-19

1981-01-13

Demers, Arthur P.

Organic compounds -- part of the class 532-570 series

Organic compounds

Amino nitrogen containing

252460, C07C10200

Patent

active

042448891

ABSTRACT:
A heterogeneous process for selectively producing acetamides in which the acyl nitrogen is otherwise bonded to methyl, ethyl, hydrogen or combinations thereof which comprises contacting a mixture of carbon monoxide, hydrogen and a nitrogen-containing compound selected from the group consisting of ammonia, nitric oxide and mixtures thereof with a heterogeneous solid catalyst comprising rhodium and manganese. The acetamides of the invention are formed in a collective amount of at least 25 weight percent of the total amide products of the reaction.

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patent: 3917661 (1975-11-01), Pruett et al.
patent: 4014913 (1977-03-01), Ellgen et al.

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