Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1979-12-26
1981-01-13
Jiles, Henry R.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
252437, C07D30760
Patent
active
042448794
ABSTRACT:
The present invention provides a method for the preparation of oxidation catalysts containing mixed oxides of vanadium and phosphorus, which catalysts are particularly effective in the oxidation of n-butane, n-butenes, 1,3-butadiene or a mixture thereof with molecular oxygen or an oxygen-containing gas in the vapor phase to produce improved yields of maleic anhydride with good selectivity. A vanadium compound is at least partially solubilized in an organic liquid medium capable of reducing at least a portion of the vanadium to a +4 valence state, and unsolubilized vanadium having a particle size larger than about 0.1 mm diameter is removed from the medium before addition of a phosphorus-containing compound.
REFERENCES:
patent: 4016105 (1977-04-01), Kerr
patent: 4132670 (1979-01-01), Katsumoto et al.
Bremer Noel J.
Dria Dennis E.
Curatolo Joseph G.
Dentz Bernard
Evans Larry W.
Jiles Henry R.
Knudsen Herbert D.
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