Aqueous free radical emulsion polymerization

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526 80, 526201, 526208, 526224, 526340, 260 2975Q, C08F 222, C08F 400

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active

041454944

ABSTRACT:
In the aqueous emulsion free radical polymerization of dienes and copolymerization of dienes and vinyl monomers using mercaptan modifiers there is added at at least 75% conversion a large amount of mercaptan modifier as compared to that previously added and the polymerization is stopped at about 90-99+% conversion to provide processable polymers having a reduced amount of or no gel.

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