Method for sox removal by catalytic carbon

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Inorganic carbon containing

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502417, 502418, 502423, 423210, 423230, 423235, 42324401, 42324403, 4232451, 95116, 95137, B01J 2118, B01J 2002, B01D 4700, C01B 1716

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active

061142735

ABSTRACT:
An improved process is provided for the removal of sulfur oxides from gas or vapor media containing oxygen and H.sub.2 O by contacting the media with a catalytically-active carbonaceous char. The improvement is provided by the use of a catalytically-active carbonaceous char prepared by low-temperature carbonization and oxidation of a bituminous coal or bituminous material at temperatures below 700.degree. C., followed by contact of the carbonized, oxidized char with one or more nitrogen-containing compounds at a temperature which is stable at, or is increasing to, temperatures less than 700.degree. C., and then increasing the temperature of the resultant material to or above 700.degree. C.

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Stohr, Brigitte et al., Enhancement of the Catalytic Activity of Activated Carbons in Oxidation Reactions by Thermal Treatment with Ammonia or Hydrogen Cyanide and Observation of a superoxide species as a possible intermediate, Carbon, pp. 707-720, 1991.

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