Process for the production of tertiary alcohols

Details Process for the production of tertiary alcohols Process for the production of tertiary alcohols

1980-03-03

1982-04-27

Evans, Joseph E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568895, 568896, 568897, 568898, 568900, 568901, C07C 2904

Patent

active

043272312

ABSTRACT:
Tertiary alcohols are produced by the hydration of an isoolefin in the presence as catalyst of an acidic cation exchange resin such as a sulfonated styrene-divinylbenzene copolymer, and a polyhydric neo-type alcohol such as neopentyl glycol. The process is useful for separating isobutylene from a hydrocarbon mixture containing its isomers via preparation of the alcohol, separation from the unreacted hydrocarbons and dehydration of the tertiary butyl alcohol to isobutylene.

REFERENCES:
patent: 3257469 (1966-06-01), Kovach
patent: 3285977 (1966-11-01), Henke et al.
patent: 3646237 (1972-02-01), Horie et al.
patent: 3965039 (1976-06-01), Chaplits et al.
patent: 4012456 (1977-03-01), Chaplits
patent: 4087471 (1978-05-01), Bowman et al.
patent: 4096194 (1978-06-01), Moy et al.
Odioso et al., "I. & E. C.", vol. 53, No. 3, Mar. 1961, pp. 209-211.

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