Method of oxidizing osmium (III) and osmium (IV) to a higher val

Details Method of oxidizing osmium (III) and osmium (IV) to a higher val Method of oxidizing osmium (III) and osmium (IV) to a higher val

1978-12-26

1980-08-12

Konopka, P. E.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

252412, 252414, 252416, 252431N, 423 22, 423592, 423593, 568860, C07F 1500, C01G 5500, B01J 2396, B01J 3118

Patent

active

042172918

ABSTRACT:
Osmium (III) or (IV) in an anionic complex with oxygen and having an alkali metal, ammonium or tetra(lower)alkylammonium cation is oxidized to a valency state higher than 5 by reaction with an organic hydroperoxide, such as ethylbenzene hydroperoxide, at a temperature less than 30.degree. C.

REFERENCES:
patent: 3317592 (1967-05-01), MacLean et al.
patent: 4049724 (1977-09-01), Sheng et al.

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