Ruthenium-phosphine complex

Details Ruthenium-phosphine complex Ruthenium-phosphine complex

1987-04-15

1988-04-19

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

C07F 1500, C07F 950

Patent

active

047390840

ABSTRACT:
A ruthenium-phosphine complex having a 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl or its derivative as a ligand and carboxyl groups bonded to the ruthenium atom thereof is disclosed. The complex is inexpensive and exhibits excellent performances as a catalyst for various organic syntheses, and particularly for asymmetric hydrogenation.

REFERENCES:
patent: 3725489 (1973-04-01), Fuhrmann et al.
patent: 3748332 (1973-07-01), Wilkinson
patent: 3793355 (1974-02-01), Wilkinson
patent: 4691037 (1987-09-01), Yoshikawa et al.

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