Method of regenerating disproportionated hydrides

Chemistry of inorganic compounds – Hydrogen or compound thereof

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423645, 423647, 423648R, C01B 600, C01B 602, C01B 624

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active

043024360

ABSTRACT:
Disclosed is a method of restoring the pressure-composition characteristics of a disproportionated hydride comprising removing substantially all hydrogen from said disproportionated hydride and maintaining said hydride in a substantially hydrogen-free environment at a regeneration temperature sufficient to effectuate desired restoration of the hydride's pressure-composition characteristics. Also disclosed are methods of insitu regeneration of hydrides in process applications.

REFERENCES:
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patent: 4039023 (1977-08-01), McClaine
patent: 4044819 (1977-08-01), Cottingham
patent: 4055962 (1977-11-01), Terry
patent: 4110425 (1978-08-01), Buhl et al.
Lynch et al., "The Role of Metal Hydrides in Hydrogen Storage and Utilization", 2nd World Hydrogen Energy Conference, Zurich, Switzerland, Aug. 21, 1978.
Yamanaka et al., "J. Chem. Soc. Japan," vol. 8, 1975, pp. 1267-1272.
Cohen et al., "Solid State Communications", vol. 25, 1978, pp. 293-295.
Buschow et al., "Hydrides for Energy Storage", from Proceedings in Geilo, Norway, Aug. 14-19, 1977, pp. 235-249.
Siegman et al. "Physical Review Letters", vol. 40, No. 11, 3 Apr., 1978, pp. 972-975.

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