Super-halogenated unsaturated polyesters and process for their m

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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260 75EP, 260 75H, 260 75UA, 260485H, 260486H, 260DIG24, 260 7841, C08G 6368

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039793680

ABSTRACT:
Super-halogenated unsaturated polyesters having average molecular weights of between 300 and 3,000, comprising units derived from at least one .alpha.-epihalohydrin and from maleic anhydride and optionally from another cyclic organic anhydride, possessing a halogen content arising from super-halogenation of between 1 and 35% by weight and the process for their manufacture which is characterized in that maleic anhydride, alone or mixed with another cyclic organic anhydride, is copolymerized with at least one .alpha.-epihalohydrin in molar ratios of epihalohydrin to anhydride(s) of between 1:1 and 2:1, in the presence of a titanium tetrahalide, the halogen being preferably chosen from the group consisting of chlorine and bromine.

REFERENCES:
patent: 3257477 (1966-06-01), Hedrick
patent: 3274293 (1966-09-01), Elfers et al.
patent: 3328485 (1967-06-01), Blaga et al.
Odian, Principles of Polymerization, McGraw-Hill, N. Y. (1970), pp. 308-310, 463 & 464.
Lenz, Organic Chemistry Of Synthetic High Polymers, Interscience Publishers, N. Y. (1967), pp. 484-493, 510-514 & 541.
Bakalo, et al., Chemical Abstracts, vol. 59, 2959h (1963).
Wolf, et al., Chemical Abstracts, vol. 72; 32,289d (1970).

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