Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1973-09-28
1976-09-07
Tillman, Murray
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
260 75EP, 260 75H, 260 75UA, 260485H, 260486H, 260DIG24, 260 7841, C08G 6368
Patent
active
039793680
ABSTRACT:
Super-halogenated unsaturated polyesters having average molecular weights of between 300 and 3,000, comprising units derived from at least one .alpha.-epihalohydrin and from maleic anhydride and optionally from another cyclic organic anhydride, possessing a halogen content arising from super-halogenation of between 1 and 35% by weight and the process for their manufacture which is characterized in that maleic anhydride, alone or mixed with another cyclic organic anhydride, is copolymerized with at least one .alpha.-epihalohydrin in molar ratios of epihalohydrin to anhydride(s) of between 1:1 and 2:1, in the presence of a titanium tetrahalide, the halogen being preferably chosen from the group consisting of chlorine and bromine.
REFERENCES:
patent: 3257477 (1966-06-01), Hedrick
patent: 3274293 (1966-09-01), Elfers et al.
patent: 3328485 (1967-06-01), Blaga et al.
Odian, Principles of Polymerization, McGraw-Hill, N. Y. (1970), pp. 308-310, 463 & 464.
Lenz, Organic Chemistry Of Synthetic High Polymers, Interscience Publishers, N. Y. (1967), pp. 484-493, 510-514 & 541.
Bakalo, et al., Chemical Abstracts, vol. 59, 2959h (1963).
Wolf, et al., Chemical Abstracts, vol. 72; 32,289d (1970).
Danison, Jr. W. C.
Solvay & Cie
Tillman Murray
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