Process for the preparation of N,O-disubstituted urethanes usefu

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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2604654, 260465D, 260404, 260239E, 260938, 560 22, 560 25, 560 27, 560 28, 560 29, 560 30, 560 31, 560 32, 560115, 560145, 560157, 560158, 560160, 560161, 544164, 544322, 546312, 546334, 549 28, 549467, C07C125065, C07C125073

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044305052

ABSTRACT:
A process for the preparation of N,O-disubstituted urethanes. Urea or polyurets, primary amines and alcohols are reacted at 120.degree.-350.degree. C. in the presence of N-substituted urethanes and/or N-mono- or N,N'-disubstituted ureas or polyureas. In a preferred embodiment, the reactants further include catalysts known to be useful in esterification of carboxylic acids. The urethanes produced in accordance with this process are particularly useful as starting materials for preparation of isocyanates.

REFERENCES:
patent: 2409712 (1946-10-01), Schweitzer
patent: 2806051 (1957-09-01), Brockway
patent: 3627813 (1971-12-01), Abbate et al.
patent: 4178455 (1979-12-01), Hirai et al.
patent: 4388238 (1983-06-01), Heitkamper et al.
Adams et al., Chemical Reviews (1965) vol. 65, 567-572.

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