Electrolytic hydrodimerization process improvement

Details Electrolytic hydrodimerization process improvement Electrolytic hydrodimerization process improvement

1975-07-28

1977-09-06

Edmundson, F.C.

Chemistry: electrical and wave energy

Processes and products

204 73A, C25B 310

Patent

active

040466515

ABSTRACT:
In a process for hydrodimerizing an olefinic nitrile, amide or ester by electrolyzing an aqueous solution of the olefinic starting material, conductive salt and a nitrilocarboxylic acid compound that inhibits formation of hydrogen at the cathode, such hydrogen formation can be even further inhibited and the current efficiency of the process significantly further increased by including in the solution a tri(C.sub.2 -C.sub.4 alkanol)amine such as triethanolamine.

REFERENCES:
patent: 3193480 (1965-07-01), Baizer et al.
patent: 3689382 (1972-09-01), Fox et al.
patent: 3830712 (1974-08-01), Campbell et al.
patent: 3898140 (1975-08-01), Lester et al.

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