Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1993-10-12
1994-12-06
Dees, Jose G.
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
C07C 6700
Patent
active
053712730
ABSTRACT:
There is disclosed a process for producing methyl methacrylate through gas-phase catalytic reaction of methyl .alpha.-hydroxyisobutyrate which comprises feeding methanol in an amount by weight of 0.1 to 3.0 times the methyl .alpha.-hydroxyisobutyrate in a reactor along therewith and proceeding with the reaction at a reaction temperature in the range of 230.degree. to 300.degree. C. by the use of a transition-type synthetic faujasite zeolite having a specific lattice constant and a specific Na content (Na/Al) as the catalyst. The process is capable of stably producing the objective product having excellent quality in high yield for a long period of time while preventing the problems of early deterioration of the catalyst and coloring of reaction product.
REFERENCES:
patent: 5068399 (1991-11-01), Naito et al.
patent: 5075493 (1991-12-01), Shima et al.
patent: 5087736 (1992-02-01), Higuchi et al.
patent: 5250729 (1993-10-01), Abe et al.
Abe Takafumi
Higuchi Hirofumi
Shima Yoshikazu
Dees Jos,e G.
Mitsubishi Gas Chemical Company Inc.
Nazario-Gonzalez Porfirio
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