Preparation of N-akenylcarbamic esters

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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560157, C07D26314

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056398905

ABSTRACT:
N-Alkenylcarbamic esters of the general formula I ##STR1## where at least one of the R.sup.1 radicals is hydrogen and the second R.sup.1 radical is hydrogen or C.sub.1 -C.sub.4 --alkyl, the R.sup.2 radical is an aliphatic, cycloaliphatic, araliphatic or aromatic radical which can be linked to the R.sup.3 radical to form a 2- to 10-membered bridge, and the R.sup.3 radical is an aliphatic, cycloaliphatic or aromatic radical, from an alkenyl carboxylate of the general formula II ##STR2## where R.sup.1 has the abovementioned meaning, and R.sup.4 is hydrogen, an aliphatic, cycloaliphatic or aromatic radical, and a carbamic ester of the general formula III ##STR3## where the R.sup.2 and R.sup.3 radicals have the abovementioned meanings, are prepared by reacting the starting compounds in the presence of a base.

REFERENCES:
patent: 3579515 (1971-05-01), Walles
patent: 4680410 (1987-07-01), Wang
patent: 4831153 (1989-05-01), Phung
patent: 5155253 (1992-10-01), Murray
patent: 5233077 (1993-08-01), Waller
"Beilsteins Handbuch Der Organischen Chemie", 1979, XP002019733, vol. 4, 4., pp. 1054-1055.
"Beilsteins Handbuch Der Organischen Chemie", 1978, XP002019666, vol. 6, 4., p. 631.
CA 76:60136c Synthesis, . . . -Oxazolidone, Culbertson et al., p. 5, 1972.
CA 113:39951n Transvinylation . . . acids. Murray, p. 549, 1990.

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