Polymerization catalyst systems, their production and use

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526130, 526156, 526160, 526170, 526901, 526904, 526943, 5263486, 502152, 502117, 502103, C08F 476, C08F 4642

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056398352

ABSTRACT:
This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The invention particularly relates to a supported metallocene catalyst system that does not require an activator or cocatalyst for the polymerization of olefins.

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Hawley's Condensed Chemical Dictionary, 11th Ed., Van Nostrand Reinhold New York, 1987; inside front cover.
Kaminsky et al., "Olefin Polymerization with Highly Active Soluble Zirconium Compounds Using Aluminoxane as Co-Catalyst", Makromol. Chem., Macromol. Symp. 3, 377-387 (1986).
Ahlers et al., "Variation of molecular weight distribution of polyethylenes obtained with homogeneous Ziegler-Natta catalysts", Makromol. Chem., Rapid Commun. 9, 457-461 (1988).
Soga et al., "Activation of SiO2-supported zirconocene catalysts by common trialkylaluminums", Makromol. Chem. 194, 3499-3504 (1993).

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