Process for producing esterified alkoxylated monoglycerides and

Organic compounds -- part of the class 532-570 series – Organic compounds – Fatty compounds having an acid moiety which contains the...

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554149, 554168, 554172, 568613, 568616, 568623, C07C 5100

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053712536

ABSTRACT:
Esterified alkoxylated mono- and diglycerides suitable for use as reduced calorie fat substitutes in food products may be produced by alkoxylating a tertiary alkyl partial ether of glycerin with an epoxide and then reacting the alkoxylated glycerin tertiary alkyl partial ether thereby obtained with a fatty acid under acid-catalyzed conditions. Separate deprotection and esterification steps are not required, resulting in a considerably streamlined process as compared to alternative methods of synthesizing alkoxylated fat substitutes having one or two fatty acid acyl groups attached directly to glycerin.

REFERENCES:
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patent: 5135683 (1992-08-01), Cooper
patent: 5266346 (1993-11-01), Klemann et al.
Applied Catalysis, 8(1983) 57-70, Elsevier Science Publishers B.V., Amsterdam-Andrew T. Guttmann & Robert K. Grasselli.
Tetrahedron Letters No. 49, pp. 4269-4270, 1970 Synthesis of Esters via Aleyl.Tert.-Butyl Ethers.

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