Modified polyester, methods of preparing same and compositions c

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525 44, 525 92, 525112, 525122, 525171, 525531, 525 63, C08L 6706, C08L 6310

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active

047757183

ABSTRACT:
An elastomeric homopolymer or copolymer is reacted with or, in effect, grafted onto an unsaturated polyester and the reaction product or graft polymer may then be used in a thermosetting unsaturated polyester resin composition. The chemical linkage between the elastomeric polymer and the unsaturated polyester is a cyclic structure comprising 6 carbon atoms. The chemical bond is achieved by first treating the elastomeric polymer to incorporate a conjugated diolefin structure and then adding the conjugated diolefin group to an ethylenically unsaturated group in the polyester or a monomeric dienophile. When added to a monomeric dienophile, the polyester is then grafted onto the elastomeric polymer at the site of the monomeric dienophile. The chemical linkage or bonding occurs through a 4+2 Diels Alder addition. The reaction or grafting effectively incorporates an elastomer segment into the thermosetting polyester resin composition and imparts improved surface characteristics and impact resistance without risk of destructive phase separation which has, heretofore, occurred when thermoplastic elastomers were incorporated into thermosetting polyester resin compositions.

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