Oxidation of organic compounds using thallium ions

Details Oxidation of organic compounds using thallium ions Oxidation of organic compounds using thallium ions

1986-12-01

1987-09-08

Demers, Arthur P.

Chemistry: electrical and wave energy

Processes and products

204 72, 204 79, 204 80, C25B 302

Patent

active

046922270

ABSTRACT:
Aqueous acidic solutions of certain thallium(III) organosulfonate having at least 0.1 molar thallium ion concentration are contacted with an organic compound to form a related oxidized organic compound. The oxidized compound is separated and recovered from the solution and the resultant thallium(I) rich solution is electrochemically treated to regenerate thallium(III) which, in turn, can be reused in a cyclical process.
The present invention provides a highly effective means of oxidizing organic substrates.

REFERENCES:
patent: 808905 (1905-12-01), Lang
patent: 3048636 (1962-08-01), Grinstead
patent: 3413203 (1968-11-01), MacLean
patent: 3486992 (1969-12-01), Frye
patent: 3641067 (1972-02-01), Kruse
patent: 3873580 (1975-03-01), Rennie
patent: 4031196 (1977-06-01), Leonard
patent: 4135051 (1979-01-01), Walker
patent: 4212710 (1980-07-01), Halter et al.
patent: 4212711 (1980-07-01), Halter et al.
patent: 4312721 (1982-01-01), Oehr
patent: 4313804 (1982-02-01), Oehr
patent: 4354904 (1982-10-01), Malloy et al.
patent: 4371431 (1983-02-01), Switzer et al.
patent: 4387007 (1983-06-01), Seiler
patent: 4482438 (1984-11-01), Ballard et al.
patent: 4530745 (1985-07-01), Komatsu et al.
patent: 4536337 (1985-08-01), Komatsu et al.
patent: 4560804 (1985-12-01), Yeh et al.
patent: 4582942 (1986-04-01), Comninellis et al.
patent: 4639298 (1987-01-01), Kreh et al.
Australian Journal of Chemistry, 32, 737-753, (1979).
J. Org. Chem., (1983), vol. 48, pp. 1487-1491 by M. Marrocco et al.
Prospects for the Indirect Electrolytic Oxidation of Organics by Ibl et al., Electro-Organic Synthesis Technology, No. 185, vol. 75, (1979), pp. 45-50.

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